4. Cristiano Ronaldo vs Barcelona
Real and great rivals Barcelona were locked at 0-0 in extra time of the 2011 King’s Cup final in Valencia and heading for penalties. Di Maria whipped a cross over from the left wing and Ronaldo leaped high above Barca defender Adriano to crash a header past keeper Jose Manuel Pinto. This goal ensured that Real Madrid won their first Copa del Rey final after 18 long years.